Alkyl-ended ansa-bis(amidinate) ligands from aliphatic primary amines and multinuclear lithium derivatives

作者:Bai Sheng Di*; Liu Rui Qin; Guan Fei; Wang Tao; Tong Hong Bo; Guo Jian Ping; Liu Dian Sheng
来源:Mendeleev Communications, 2013, 23(5): 265-267.
DOI:10.1016/j.mencom.2013.09.009

摘要

A practical synthetic pathway to alkyl-ended ansa-bis(amidinate) ligands was developed via linking the freshly prepared aliphatic group substituted lithium amidinate and the subsequent deprotonation. The lithium complexes prepared by this method were characterized by NMR spectroscopy, elemental analysis and single-crystal X-ray diffraction analysis.

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