Hydrothermal Synthesis and Crystal Structure of Binuclear Complex [Cd(5-ClHsal)(2)(2,2 '-bipy)](2)

作者：Jiang Xiu Rong; Dong Yan; Chen Wu Hua; Wen De Cai^*

来源：Asian Journal of Chemistry, 2012, 24(6): 2813-2814.

• Hydrothermal synthesis
• Crystal structure
• Cd(II) complex
• Binuclear

A novel cadmium complex [Cd(5-ClHsal)(2)(2,2'-bipy)(H2O)](2) (5-ClHsal = 5-chlorosalicylate anion, 2,2'-bipy = 2,2'-bipyridine) was synthesized by hydrothermal reaction and characterized by elemental analysis and X-ray single crystal diffraction. The crystal is monoclinic, space group P2(1)/c with a = 9.138(3) angstrom, b= 17.174(6) angstrom, c = 16.174(5) angstrom, alpha = 90 degrees, beta = 106.06(1)degrees, gamma = 90 degrees, Mn = 1259.41,V = 2439(1)angstrom(3), Dc = 1.715 g/cm(3), F(000) = 1256 and Z = 2. The structure analysis shows that the complex exhibits a binuclear structure. The adjacent binuclear molecules are connected together by the hydrogen bonds to 1D supramolecular chain structure. The crystal structure is stabilized by hydrogen bonds and pi-pi stacking interactions.

• 出版日期2012-6
• 单位龙岩学院