A Flexible Enantioselective Total Synthesis of Diospongins A and B and Their Enantiomers Using Catalytic Hetero-Diels-Alder/Rh-Catalyed 1,4-Addtion and Asymmetric Transfer Hydrogenation Reactions as Key Steps

作者：Kumaraswamy Gullapalli^*; Ramkrishna Gajula; Naresh Police; Jagadeesh Bharatam; Sridhar Balasubramanian

来源：Journal of Organic Chemistry, 2009, 74(21): 8468-8471.

A unified enantioselective route to total synthesis of diospongins A and B and their enantiomers has been developed employing achiral starting materials. All three stereocenters were introduced by means of catalytic reactions.

• 出版日期2009-11-6