摘要
With the aid of a bifunctional 6-mercaptonicotinic acid ligand, a novel {Ni12Gd24} cage-based (6, 12)-c alb-MROF that is assembled from a {Gd-4(OH)(4)(COO)(6)} trigonal-prism building unit and a {Ni6S12} hexagonal-prism molecular building block has been synthesized for the first time. It exhibits a large MCE value of 29.86 J kg(-1) K-1 for Delta H = 8 T at 2 K.
- 出版日期2017-8-21
- 单位结构化学国家重点实验室; 中国科学院福建物质结构研究所; 福州大学