Mu(III) Salen-type Single-molecule Magnet Fixed in a Two-dimensional Network

作者：Kachi Terajima Chihiro^*; Mori Erina; Eiba Tasuku; Saito Toshiaki; Kanadani Chikahide; Kitazawa Takafumi; Miyasaka Hitoshi

来源：Chemistry Letters, 2010, 39(2): 94-95.

DOI：10.1246/cl.2010.94

A two-dimensional network Compound, [{Mn(saltmen)}(4)-{Co(CN)(6)}](ClO4)center dot 9H(2)O (2) (saltmen(2-) = N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneiminate)), was synthesized. Magnetic measurements characterized the [Mn-2(saltmen)(2)](2+) Subunit its it single-molecule magnet with an S-T = 4 spin ground state, indicating that the Mn-III dinier is magnetically isolated not only by the diamagnetic [Co(CN)(6)](3-) Unit but also by the space between the layers.

• 出版日期2010-2-5