Analysis of mid-infrared photoluminescence around 2.85 mu m in Yb3+/Ho3+ co-doped synthetic silica-germanate glass

作者:Cao, Wenqian; Wang, Tao; Huang, Feifei*; Ye, Renguang; Lei, Ruoshan*; Tian, Ying; Zhang, Junjie; Xu, Shiqing
来源:Infrared Physics & Technology, 2018, 89: 363-368.
DOI:10.1016/j.infrared.2018.01.031

摘要

2.85 mu m fluorescence of Ho3+ was firstly obtained in Yb3+/Ho3+ co-doped silica-germanate glass. The combination of low OH-concentration and high mid -infrared transmittance were beneficial to the realization of mid-infrared emissions. A large calculated spontaneous radiative transition probability (30.27 s(-1)) corresponding to the Ho3+:I-5(6) -> I-5(7) transition was beneficial for high gain and more opportunity to achieve laser action. Besides, enhanced green (548 nm) and red (662 nm) emissions were obtained due to the energy transfer between Yb3+ and Ho3+ Moreover, the measured lifetime of Ho3+:816 reached as high as 283 mu s in Yb3+/Ho3+ co-doped silica-germanate glass, which also possesses a large emission cross section (8.05 x 10(-21) cm(2)). All results reveal that Yb3+/Ho3+ co-doped silica-germanate glass might provide a new choice for 2.85 mu m laser applications.