Hybrid Polyhedral Oligomeric Silsesquioxanes-Imides with Tailored Intercage Spacing for Sieving of Hot Gases

作者:Raaijmakers Michiel J T; Wessling Matthias; Nijmeijer Arian; Benes Nieck E*
来源:Chemistry of Materials, 2014, 26(12): 3660-3664.
DOI:10.1021/cm500691e

摘要

Macromolecular network rigidity of synthetic membranes is essential for sieving of hot gases. Hyper-cross-linked polyPOSS-imide membranes with tailored intercage spacing are presented. The length and flexibility of their imide bridges enables tuning of gas permeability and selectivity in a broad temperature range. The facile synthesis allows for large-scale production of membranes designed for specific process conditions.

  • 出版日期2014-6-24