Degradation of beta-carotene in amorphous polymer matrices. Effect of water sorption properties and physical state

作者:Ramoneda Ximena A; Ponce Cevallos Peggy A; del Pilar Buera Maria; Elizalde Beatriz E*
来源:Journal of the Science of Food and Agriculture, 2011, 91(14): 2587-2593.
DOI:10.1002/jsfa.4497

摘要

BACKGROUND: The use of encapsulation in amorphous matrices of carbohydrate and/or polymer formed during dehydration processes to enhance the stability and retention of labile compounds is increasing in the food and pharmaceutical industries. Efforts to improve encapsulating properties have been made using mixtures of carbohydrates with proteins or gums in different proportions. The objective of the present work was to study the stability of encapsulated beta-carotene and its degradation kinetics in maltodextrin/gum arabic and maltodextrin/gelatin matrices in relation to the physical properties and state of the dehydrated matrix. RESULTS: The degradation of beta-carotene followed a first-order kinetic model of fractional retention for all encapsulating matrices. The Guggenheim-Anderson-de Boer (GAB) model was adequate to describe the sorption isotherms of the studied systems. beta-Carotene losses were observed mainly at relative humidities (RHs) above the glass transition temperatures (T-g) of the corresponding systems, where the matrices were fully plasticised and collapsed (75 and 92% RH). At these high RHs the best beta-carotene retention was obtained in the system containing gum arabic. CONCLUSION: The results showed that pigment degradation was determined by the physical state of the matrix, related to the degree of collapse. They represent a contribution to the knowledge of physical factors that affect the retention kinetics of labile biomolecules encapsulated in dehydrated matrices.

  • 出版日期2011-11