A dinuclear copper(II) complex and a zigzag chain iron(II) polymer based on the 4-antipyrine derived Schiff base ligands: The hydroxylation and redox occurred under the solvothermal conditions

作者：Wang Xian Wen^*; Zheng Yue Qing

来源：Inorganic Chemistry Communications, 2007, 10(6): 709-712.

DOI：10.1016/j.inoche.2007.03.008

• dinuclear copper(II)
• iron(II) polymer
• solvothermal synthese
• methyl group hydroxylation
• redox

A new dinuclear copper(II) compound, [Cu-2(L1-O)(2)] (1) (L1 = (4E)-4-(2-hydroxybenzylideneamino)-1,2-dihydro-2,3-dimethyl-lphenylpyrazol-5-one), and zigzag chain polymer, {[FeCl2(L2)]}(n), (2) (L2=1,5-dimethyl-2-phenyl-4-f[(1E)-pyridine-4-ylmethylene]amino}-1,2-dihydro-3 H-pyrazol-3-one), were synthesized by solvothermal reactions and structurally characterized. The methyl group hydroxylation and the redox have been observed in the preparation of 1 and 2, respectively.

• 出版日期2007-6
• 单位宁波大学; 中国地质大学（北京）