A pillared metal-organic framework incorporated with 1,2,3-triazole moieties exhibiting remarkable enhancement of CO2 uptake

作者：Gao Wen Yang; Yan Wuming; Cai Rong; Williams Kia; Salas Andrea; Wojtas Lukasz; Shi Xiaodong^*; Ma Shengqian

来源：Chemical communications, 2012, 48(71): 8898-8900.

DOI：10.1039/c2cc34380k

The replacement of the pillar ligand, 4,4%26apos;-bipyridine, in the prototypal pillared MOF, MOF-508, with the custom-designed ligand, 4,4%26apos;-(2H-1,2,3-triazole-2,4-diyl) dipyridine, affords a porous metal-triazolate framework, MTAF-3, which demonstrates remarkable enhancement of CO2 uptake capacity by a factor of similar to 3 compared to the parent MOF-508.

• 出版日期2012