Modified hydrothermal synthesis and characterization of reduced graphene oxide-silver selenide nanocomposites with enhanced reactive oxygen species generation

作者：Zhu Lei; Ye Shu; Ali Asghar; Ulla Kefayat; Cho Kwang Youn; Oh Won Chun^*

来源：Chinese Journal of Catalysis, 2015, 36(4): 603-611.

DOI：10.1016/S1872-2067(14)60275-8

• Graphene
• Silver selenide
• Sono chemical method
• Hydrothermal method
• Rhodamine B
• Texbrite BA-L

A visible-light photocatalyst containing Ag2Se and reduced graphene oxide (RGO) was synthesized by a facile sonochemical-assisted hydrothermal method. X-ray diffraction, scanning electron microscopy with energy-dispersive X-ray analysis, and ultraviolet-visible diffuse reflectance spectroscopy results indicated that the RGO-Ag2Se nanocomposite contained small crystalline Ag2Se nanoparticles dispersed over graphene nanosheets and absorbed visible light The high crystallinity of the nanoparticles increased photocatalytic activity by facilitating charge transport. N-2 adsorption-desorption measurements revealed that the RGO-Ag2Se nanocomposite contained numerous pores with an average diameter of 9 nm, which should allow reactant molecules to readily access the Ag2Se nanoparticles. The RGO-Ag2Se nanocomposite exhibited higher photocatalytic activity than bulk Ag2Se nanoparticles to degrade organic pollutant rhodamine B and industrial dye Texbrite BA-L under visible-light irradiation (lambda > 420 nm). The generation of reactive oxygen species in RGO-Ag2Se was evaluated through its ability to oxidize 1,5-diphenylcarbazide to 1,5-diphenylcarbazone. The small size of the Ag2Se nanoparticles in RGO-Ag2Se was related to the use of ultrasonication during their formation, revealing that this approach is attractive to form porou

• 出版日期2015-4