Asymmetric organocatalytic synthesis of tertiary azomethyl alcohols: key intermediates towards azoxy compounds and alpha-hydroxy-beta-amino esters

作者:Carmona Jose A; de Gonzalo Gonzalo; Serrano Inmaculada; Crespo Pena Ana M; Simek Michal; Monge David; Fernandez Rosario; Lassaletta Jose M
来源:Organic and Biomolecular Chemistry, 2017, 15(14): 2993-3005.
DOI:10.1039/c7ob00308k

摘要

New carbohydrate based organocatalysts have been developed for the asymmetric nucleophilic addition of formaldehyde tert-butylhydrazone to α-keto esters.

  • 出版日期2017-4-14