A Novel Reaction of 10-Methylacridinium with Reactive Metals under Grinding

作者：Xu Huajian^*; Xu Xiaolan; Feng Yisi

来源：Chinese Journal of Organic Chemistry, 2009, 29(2): 289-291.

• coenzyme NADH model
• solid phase
• grinding
• electron transfer

Under grinding, 10-methylacridinium iodide was reacted with alkaline metal Li, Na, or K to give 9,10-dihydro-10-methylacridine (AcrH(2)), and 9,10-dihydro-10-methyl-9-acridone (Acr=O) in excellent yields, which can be understood in terms of an initial electron transfer from metal to 10-methylacridinium iodide.

• 出版日期2009-2
• 单位合肥工业大学; 安徽医科大学