Potassium salt of salicylidene-beta-hydroxyalanine

作者:Gao Xu Sheng; Wan Yong Min; Lv Zhi Fang; Shi Yuan Xiang; Wang Jin Tang*
来源:Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M2370-U1130.
DOI:10.1107/S1600536807040329

摘要

The title compound, poly[[ mu-3-hydroxy-2-(2-hydroxybenzylideneamino) propionato] potassium], [K( C10H10NO4)](n), is an effective material for preparing rare earth Eu complexes. It is composed of planar six-membered rings and planar five-membered rings formed by intramolecular O - H center dot center dot center dot N hydrogen bonding, which are oriented with respect to each other at a dihedral angle of 3.56 ( 4)degrees. The K+ ion is surrounded by seven O atoms, five from three carboxylate groups and two from two hydroxyl groups. In the crystal structure, intermolecular O - H center dot center dot center dot O hydrogen bonds result in the formation of chains along the c axis.