A molecular layer "fabric" with orthogonally woven coordination polymer chains

作者：Mizzi Jessica E; LaDuca Robert L^*

来源：Inorganic Chemistry Communications, 2016, 70: 4-6.

DOI：10.1016/j.inoche.2016.05.017

• Coordination complex
• Copper
• Crystal structure
• Weaving
• Layer

Crystals of [Cu(ox)(dpa)(H2O)](n) (1, ox = oxalate, dpa = 4,4'-dipyridylamine) were prepared by hydrothermal reaction of potassium copper oxalate and dpa. Single-crystal X-ray diffraction showed the formation of orthogonally oriented sets of 1D [Cu(ox)(dpa)(H2O)](n) chains that interlock in a 1D + 1D -> 2D manner to form woven "warp-and-woof" supramolecular layers. Thermogravimetric analysis indicated that the structure of 1 remained stable to about 175 degrees C.

• 出版日期2016-8