2D structure with rectangular grids woven by coordination chains and pseudo-metal wires

作者：Zhang, HX; Kang, BS^*; Deng, LR; Ren, C; Su, CY; Chen, ZN

来源：Inorganic Chemistry Communications, 2001, 4(1): 41-44.

DOI：10.1016/S1387-7003(00)00191-X

• cyanide complex
• coordination polymer
• Ag-Ag interactions
• metal wire

A heterometallic assembly, [{Cd(en)(2)Ag(CN)(2)} {Ag(CN)(2)}](n), has been synthesized and structurally characterized. The 2D layered structure is constructed by interweaving the coordination chains of {Cd(en)(2)Ag(CN)(2)}( ) containing Cd-N equivalent toC-Ag linkage with the pseudo-metal wires formed by the anions [Ag(CN)(2)](-) and Ag(I) of the chains through Ag-Ag interactions.

• 出版日期2001-1
• 单位中山大学