Phase evolution and microwave dielectric properties of Bi3SbO7 ceramic

作者:Pang Li Xia*; Zhou Di; Wang Hong; Wu Ying; Guo Jing; Chen Yue Hua
来源:Journal of Physics and Chemistry of Solids, 2011, 72(7): 882-885.
DOI:10.1016/j.jpcs.2011.04.011

摘要

The Bi3SbO7 ceramic was prepared by the solid state reaction method and its phase evolution at different temperatures was studied. Low temperature phase alpha-Bi3SbO7 was formed at about 890 degrees C and it started to transform to high temperature phase beta-Bi3SbO7 at about 960 degrees C. Microwave dielectric constants of alpha-Bi3SbO7 ceramic and beta-Bi3SbO7 ceramic were 43.2 and 37.6, Qf value were 2080 and 5080 GHz, respectively. TCF of alpha-Bi3SbO7 ceramic was near zero and TCF of beta-Bi3SbO7 ceramic was about -120 ppm/degrees C. The Bi3SbO7 ceramic is a promising candidate for low temperature co-fired ceramic (LTCC) technology due to its large dielectric constant, low dielectric loss at microwave region, low sintering temperature and simple composition.