Multinuclear solid-state NMR study: a powerful tool for understanding the structure of ZnO hybrid nanoparticlesd

作者：Spataro Gregory; Champouret Yohan; Florian Pierre; Coppel Yannik^*; Kahn Myrtil L^*

来源：Physical Chemistry Chemical Physics, 2018, 20(18): 12413-12421.

DOI：10.1039/c8cp01096j

Characterization of hybrid materials is crucial for gaining an in-depth understanding of nano-objects. Here, it is evidenced that the use of multinuclear H-1, H-2, C-13, N-15, Zn-67 and O-17 MAS NMR spectroscopy is a very powerful approach to acquire both structural and dynamic information on hybrid ZnO nanomaterials prepared from an organometallic approach. Not only is the coordination mode of the organic part onto the inorganic surface evidenced but also important information about the dynamics of the organic capping molecules and some particularities of the nanocrystal structure itself are obtained.

• 出版日期2018-5-14