Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

作者:Kuriyama Shogo; Arashiba Kazuya; Nakajima Kazunari; Tanaka Hiromasa; Yoshizawa Kazunari; Nishibayashi Yoshiaki
来源:European Journal of Inorganic Chemistry, 2016, 2016(30): 4856-4861.
DOI:10.1002/ejic.201601051

摘要

A series of azaferrocene-based PNP-type pincer ligands were designed and prepared as new PNP-type pincer ligands. Some transition-metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene-based PNP-type pincer ligands were also prepared and characterized by X-ray analysis. The stoichiometric and catalytic reactivities of molybdenum-dinitrogen complexes toward nitrogen fixation were investigated in detail.

  • 出版日期2016-10