Aerobic oxidation of cumene catalysed by 4-alkyloxycarbonyl-N-hydroxyphthalimide

作者:Kasperczyk Kornela*; Orlinska Beata; Zawadiak Jan
来源:CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2014, 12(11): 1176-1182.
DOI:10.2478/s11532-014-0565-8

摘要

4-Hexyloxycarbonyl-, 4-dodecyloxycarbonyl- and 4-hexadecyloxycarbonyl-N-hydroxyphthalimides were synthesised using trimellitic anhydride chloride as the starting material. The obtained lipophilic derivatives of N-hydroxyphthalimide were applied as catalysts of the cumene oxidation reaction with oxygen performed in polar acetonitrile, in non-polar tert-butylbenzene and in the absence of a solvent. The courses of reactions catalysed by N-hydroxyphthalimide and its derivatives were compared.

  • 出版日期2014-11