Mild Conditions for Oxidation/Epoxidation of Styrene

作者：Kazanci A; Saribiyik O Y^*; Serin S

来源：Designed Monomers and Polymers, 2011, 14(6): 559-570.

DOI：10.1163/156855511X598641

• Schiff base
• styrene
• oxidation
• catalytic activity

In this study, in order to obtain novel support materials for immobilization of transition metals, polymeric Schiff bases were synthesized using a poly-condensation reaction between ortho(o-)phthalaldehyde tere(t-)phthalaldehyde, oxaldehyde and diamines like, e.g., ethylene-p-phenylene-and o-phenylenediamine. Additionally, catalytic activity of polymeric Schiff base metal on oxidation/epoxidation of styrene complexes were investigated. The products have been characterized on the basis of analytical and spectral method, Fourier transform infrared spectroscopy, (1)H- and (13)C-nuclear magnetic resonance, gel-permeation chromatography, elemental analysis, thermogravimetric analysis, atomic adsorbtion spectrometry, gas chromatography and gas chromatography mass spectrometry.

• 出版日期2011