Microwave-induced low temperature pyrolysis of macroalgae for unprecedented hydrogen-enriched syngas production

作者:Bermudez Jose M; Francavilla Matteo; Calvo Esther G; Arenillas Ana; Franchi Massimo; Angel Menendez J; Luque Rafael
来源:RSC Advances, 2014, 4(72): 38144-38151.
DOI:10.1039/c4ra05372a

摘要

An efficient methodology based on low temperature microwave-induced pyrolysis has been developed for syngas production from macroalgae. The protocol provided unprecedented hydrogen production, with switchable H-2/CO ratios depending on pyrolysis conditions which were found to remarkably improve conventional pyrolysis experiments even at significantly higher temperatures (400 vs. 800 degrees C). Arcing effects under microwave irradiation, which result in an interesting observed pseudo-catalytic effect promoted by the metal oxides contained in macroalgae, seem to account for the improved results.

  • 出版日期2014