A new luminescent 3D metal-organic framework possessing a rare (3,5)-connected net which can be transformed from a 2D double layer

作者：He Haiyan; Dai Fangna; Sun Daofeng^*

来源：Dalton Transactions, 2009, (5): 763-766.

DOI：10.1039/b815935a

Applying a nonplanar dicarboxylate ligand, a new 3D metal-organic framework, Zn(TBDC(1))(1/2)(TBDC(2))(1/2) (1), possessing a rare (3,5)-connected net has been synthesized and characterized; complex 1 can be formed from a 2D double layer by thermally liberating the coordinated water and dmf molecules, simultaneous with luminescence-increased changes.

• 出版日期2009
• 单位山东大学