Novel C-N bond cleavage and formation in the polyoxometalates-catalyzed oxidation of nitroaromatics with 30% aqueous H2O2: An unprecedented disproportionation of nitroaromatics affording dinitroaromatics

作者：Gao FX; Hua RM^*

来源：Inorganica Chimica Acta, 2005, 358(13): 4045-4048.

DOI：10.1016/j.ica.2005.07.004

• catalytic disproportionation
• hydrogen peroxide
• nitroaromatic compounds
• polyoxometalate

In the presence of catalytic amount of K7NiV13O38 (.) 16H2O and 30% aqueous hydrogen peroxide, the disproportionation of nitroaromatic compounds occurs to give dinitro-substituted aromatic compounds. This novel disproportionation has disclosed an unprecedented process in which the carbon-nitrogen bond is catalytically cleaved and formed.

• 出版日期2005-9-1
• 单位清华大学