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摘要
The alkynylselenolatoalkylidyne complex [Mo( C-Se-C CSiMe(3))(CO)(2){HB(pzMe(2))(3)}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh(3))(3)] via an unusual C-Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(mu(perpendicular to)-SeCC CSiMe(3))Cl(CO)(2)(PPh(3)){HB(pzMe(2))(3)}], the crystal structure of which reveals a RhMoCSe tetrahedrane core.
- 出版日期2010-4-12
