Direct visualization of a self-organized multilayer film of low T-g diblock copolymer micelles

作者：Smith Emelyn G; Webber Grant B; Sakai Kenichi; Biggs Simon; Armes Steven P; Wanless Erica J^*

来源：Journal of Physical Chemistry B, 2007, 111(20): 5536-5541.

DOI：10.1021/jp072231z

The first in situ proof of the presence of true nanoscale micelle structure within alternating layers of a self-assembled cationic and anionic diblock copolymer micelle-micelle multilayer film is presented using atomic force microscopy. Apparently similar layer morphologies are distinguished by the interaction force curves normal to each layer. The three-dimensional order in these low T-g diblock copolymer films, together with their mechanical resilience and strongly hydrated nature, suggests many new technological applications.

• 出版日期2007-5-24