Novel pendant azobenzene/polymer systems for second harmonic generation and optical data storage

作者：Spiridon Mitica Cezar; Iliopoulos Konstantinos^*; Jerca Florica Adriana; Jerca Valentin Victor; Vuluga Dumitru Mircea; Vasilescu Dan Sorin; Gindre Denis; Sahraoui Bouchta

来源：Dyes and Pigments, 2015, 114: 24-32.

DOI：10.1016/j.dyepig.2014.10.010

• Azo-monomer
• SHG microscopy
• Side-chain azo-polymer
• H-aggregates
• Nonlinear optics (NLO)
• Chromophore-chromophore aggregation

New poly(methyl methacrylate)s bearing push-pull azo-moieties, with the azo-dye content ranging from 31 wt% to 100 wt%, are synthesized by (co)polymerization of a methacrylamide-based azo-monomer. The high reactivity of the colored monomer allowed well-balanced structures to be achieved, characterized by a suitable thermal stability. The second harmonic generation efficiency of the poled samples is investigated by means of the SHG Maker fringes setup. Features that hinder the translation of the azo-moiety optical nonlinearity in the material at the macroscopic level are debated. The results underline the role of chromophore chromophore and chromophore polymer interactions on the alignment of the azo-moieties. The polarity of the polymer matrix is proven to influence the chromophore chromophore interactions. Two-photon absorption is employed for gray scale encoding of second harmonic signals on poled thin films, thus pointing out the possibility to employ these new materials for optical data storage applications.

• 出版日期2015-3