Adsorption of hydrogen on nanoporous carbon adsorbents

作者：Fomkin A A^*; Sinitsyn V A; Gur'yanov V V

来源：Russian Chemical Bulletin, 2009, 58(4): 712-716.

DOI：10.1007/s11172-009-0082-7

• adsorption
• hydrogen
• microporous carbon adsorbents
• model adsorbents
• porous structure
• theory of volumetric filling of micropores
• high pressures

Four samples of active carbons with specific micropore volumes of 0.4-1.33 cm(3)g(-1) at 77 K and pressures up to 5 MPa were used to study hydrogen adsorption. The highest amount of of hydrogen adsorbed on these active carbons at the boiling point 20.38 K and pressure 0.101 MPa was calculated by methods derived from the theory of volumetric filling of micropores (TVFM). The adsorbent FAS-1-05 prepared by the liquid-phase polymerization of furfurol was shown to have the highest adsorption capacity. The amounts of hydrogen adsorbed on FAS-1-05 at temperatures 77, 196, and 300 K and pressures 7 and 20 MPa were calculated using the TVFM methods with allowance for linearity of the isosters. The results were compared with the experimental values obtained at 77 K and pressure below 5.1 MPa and at 293 K and pressures up to 16.1 MPa. The highest amounts of hydrogen adsorbed (6.2 wt.% for the adsorbent FAS-1-05) were obtained under pressures below 5.1 MPa and at 77 K.

• 出版日期2009-4