Multi-wall carbon nanotube counter electrodes for dye-sensitized solar cells prepared by electrophoretic deposition

作者：Lin Jeng Yu^*; Lien Chih Heng; Chou Shu Wei

来源：Journal of Solid State Electrochemistry, 2012, 16(4): 1415-1421.

DOI：10.1007/s10008-011-1541-2

• Multi-wall carbon nanotube
• Electrophoretic deposition
• Electrocatalytic activity
• Counter electrode
• Dye-sensitized solar cell

In this study, electrophoretic deposition (EPD) was employed to fabricate multi-wall carbon nanotube (MWCNT) counter electrodes (CEs) for dye-sensitized solar cells (DSSCs). Firstly, raw MWCNTs were functionalized by means of an acid mixture solution and then subjected to EPD. The results obtained from Raman spectroscopy, Fourier transform infrared spectroscopy, field-emission scanning electron microscope, and cyclic voltammogram demonstrated that the defects and open ends on the MWCNTs can be obtained via chemical functionalization and thus facilitate the enhancement in the electrocatalytic activity for I (3) (-) reduction of MWCNT CEs. In addition to optimizing chemical functionalization of MWCNTs surface, the optimal thickness of MWCNT CEs prepared by EPD was also investigated. Additionally, consecutive cyclic voltammetric tests demonstrated that the MWCNT CE fabricated by EPD possessed excellent electrochemical stability. In comparison with MWCNT CEs fabricated by tape-casting approach, MWCNT CEs prepared by EPD presented a superior adhesion between MWCNT deposits and conducting glass substrates. Therefore, MWCNT CEs fabricated by EPD can be of great potential for use in low-cost plastic DSSCs.

• 出版日期2012-4
• 单位清华大学