An unprecedented trinuclear Fe-II triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature

作者：Pittala Narsimhulu; Thetiot Franck; Charles Catherine; Triki Smail^*; Boukheddaden Kamel; Chastanet Guillaume; Marchivie Mathieu

来源：Chemical communications, 2017, 53(59): 8356-8359.

DOI：10.1039/c7cc04112h

We report a triazole-based trinuclear complex as the first example that displays a complete one-step first-order [HS-HS-HS] 2[LS-LS-LS] spin transition at 318 K. The strong ferro-elastic interactions, between the three metal centers, have been identified as the source of the concerted spin transition in this trinuclear complex.

• 出版日期2017-7-28