Nonionic block copolymer and anionic mixed surfactants directed synthesis of highly ordered mesoporous silica with bicontinuous cubic structure

作者：Chen DH; Li Z; Yu CZ; Shi YF; Zhang ZD; Tu B; Zhao DY^*

来源：Chemistry of Materials, 2005, 17(12): 3228-3234.

DOI：10.1021/cm050209h

Mesoporous silica with Ia (3) over bard structure has been successfully prepared by using mixed surfactants of commercially available nonionic block copolymer P123 (EO(20)PO(70)EO(20)) and anionic sodium dodecyl sulfate (SDS) as structure-directing agents through an acid-catalyzed silica sol-gel process. XRD, TEM, and N(2) sorption measurements show that the products have highly ordered bicontinuous cubic mesostructure with high surface area (similar to 770 m(2)/g), large pore volume (similar to 1.5 cm(3)/g) and uniform pore size (similar to 10 nm). Effects of preparation parameters on the formation of the mesostructure have been extensively investigated. It is found that the molar ratios of SDS/P123 between 2.1 and 2.5 and that of silicic species to P123 in the range from 40 to 75 are favorable for the formation of highly ordered Ia (3) over bard mesostructure. Prolonging hydrothermal treatment time leads to almost unchanged cell parameters of the products, whereas there is obvious increase of the pore sizes and pore volume. The results show that resultant template-free mesoporous silica products have excellent thermal stability, and they are more stable in N2 atmosphere than in air. Morphologies of the resultant materials can be further controlled by adding inorganic salt (such as Na(2)SO(4)) into the mixed surfactants system. Coral- and petaline-like mesoporous silica with continuous skeletons can be obtained. Understanding this synthesis system might be useful for economical and large-scale production of mesoporous materials with controllable structures.

• 出版日期2005-6-14
• 单位复旦大学