Assembly of a calix[4]arene-supported (MnMnII)-Mn-III cluster mediated by halogen interactions

作者：Taylor Stephanie M^*; Frost Jamie M; McLellan Ross; McIntosh Ruaraidh D; Brechin Euan K; Dalgarno Scott J

来源：CrystEngComm, 2014, 16(35): 8098-8101.

DOI：10.1039/c4ce00729h

A new calix[4]arene-supported (MnMnII)-Mn-III cluster, formed by the introduction of 3,5-dichlorobenzoate to a system known to afford (Mn2Mn2II)-Mn-III Single-Molecule Magnets (SMMs), assembles in a layered manner through halogen interactions; structural and magnetic properties of this new cluster are presented.

• 出版日期2014