A weak-base fibrous anion exchanger effective for rapid phosphate removal from water

作者：Awual Md Rabiul^*; Jyo Akinori; El Safty Sherif A; Tamada Masao; Seko Noriaki

来源：Journal of Hazardous Materials, 2011, 188(1-3): 164-171.

DOI：10.1016/j.jhazmat.2011.01.092

• Weak-base fibers
• Phosphate
• High selectivity
• Competing anions
• Breakthrough point
• Anion exchange
• Rapid phosphate removal

This work investigated that weak-base anion exchange fibers named FVA-c and FVA-f were selectively and rapidly taken up phosphate from water. The chemical structure of both FVA-c and FVA-f was the same; i.e., poly(vinylamine) chains grafted onto polyethylene coated polypropylene fibers. Batch study using FVA-c clarified that this preferred phosphate to chloride, nitrate and sulfate in neutral pH region and an equilibrium capacity of FVA-c for phosphate was from 2.45 to 6.87 mmol/g. Column study using FVA-f made it clear that breakthrough capacities of FVA-f were not strongly affected by flow rates from 150 to 2000h(-1) as well as phosphate feed concentration from 0.072 to 1.6 mM. Under these conditions, breakthrough capacities were from 0.84 to 1.43 mmol/g indicating high kinetic performances. Trace concentration of phosphate was also removed from feeds containing 0.021 and 0.035 mM of phosphate at high feed flow rate of 2500 h(-1), breakthrough capacities were 0.676 and 0.741 mmol/g, respectively. The column study also clarified that chloride and sulfate did not strongly interfere with phosphate uptake even in their presence of equimolar and fivefold molar levels. Adsorbed phosphate on FVA-f was quantitatively eluted with 1 M HCl acid and regenerated into hydrochloride form simultaneously for next phosphate adsorption operation. Therefore. FVA-f is able to use long time even under rigorous chemical treatment of multiple regeneration/reuse cycles without any noticeable deterioration.

• 出版日期2011-4-15