A ketone/alcohol polymer for cycle of electrolytic hydrogen-fixing with water and releasing under mild conditions

作者：Kato Ryo; Yoshimasa Keisuke; Egashira Tatsuya; Oya Takahiro; Oyaizu Kenichi; Nishide Hiroyuki

来源：Nature Communications, 2016, 7(1): 13032.

DOI：10.1038/ncomms13032

Finding a safe and efficient carrier of hydrogen is a major challenge. Recently, hydrogenated organic compounds have been studied as hydrogen storage materials because of their ability to stably and reversibly store hydrogen by forming chemical bonds; however, these compounds often suffer from safety issues and are usually hydrogenated with hydrogen at high pressure and/or temperature. Here we present a ketone (fluorenone) polymer that can be moulded as a plastic sheet and fixes hydrogen via a simple electrolytic hydrogenation at -1.5V (versus Ag/AgCl) in water at room temperature. The hydrogenated alcohol derivative (the fluorenol polymer) reversibly releases hydrogen by heating (80 degrees C) in the presence of an aqueous iridium catalyst. Both the use of a ketone polymer and the efficient hydrogen fixing with water as a proton source are completely different from other (de) hydrogenated compounds and hydrogenation processes. The easy handling and mouldable polymers could suggest a pocketable hydrogen carrier.

• 出版日期2016-9