A new method of synthesis of the B3H (8) (-) anion

作者：Bykov A Yu^*; Razgonyaeva G A; Mal'tseva N N; Zhizhin K Yu; Kuznetsov N T

来源：Russian Journal of Inorganic Chemistry, 2012, 57(4): 471-473.

DOI：10.1134/S0036023612040055

A new method of synthesis of the B3H (8) (-) anion has been suggested. The method uses the reaction of some metal halides (CuCl, SnCl2, CrCl3, PbF2, PbCl2, PbBr2, and BiCl3) with sodium tetrahydroborate. It is characterized by high (up to quantitative) yields and simplicity of isolation of the target products ((n-C4H9)(4)N)[B3H8] and Cs[B3H8].

• 出版日期2012-4