A highly selective synthesis of dialkenyl sulfones via cross-metathesis of divinyl sulfone

作者:Bieniek Michal*; Koloda Dariusz; Grela Karol
来源:Organic Letters, 2006, 8(25): 5689-5692.
DOI:10.1021/ol061991

摘要

Catalytic cross-metathesis of commercial divinyl sulfone allowed direct access to novel (E)-alkenylvinyl sulfones and (E, E)- dialkenyl sulfones with excellent stereoselectivity. These compounds are useful building blocks, e. g., in the synthesis of substituted thiomorpholine 1,1-dioxide derivatives.

  • 出版日期2006-12-7