Alloying of Fe3O4 and Co3O4 to develop Co3xFe3(1-x)O4 ferrite with high magnetic squareness, tunable ferromagnetic parameters, and exchange bias

作者：Bhowmik R N^*; Vasanthi V; Poddar Asok

来源：Journal of Alloys and Compounds, 2013, 578: 585-594.

DOI：10.1016/j.jallcom.2013.06.160

• Ferrite composite
• Freezing of ferromagnetic domains
• Magnetic squareness
• Exchange bias
• Domain wall pinning

Ferromagnetic (FM) Fe3O4 and antiferromagnetic (AFM) Co3O4 has been alloyed to form the ferrite composition Co3xFe3(1-x)O4 (x = 0.1, 0.3, 0.5). Three different routes, viz., mechanical alloying at room temperature, annealing of the mechanically alloyed sample and solid state sintering, have been followed to develop the ferrite. X-ray diffraction pattern showed incomplete alloying in as milled samples. Single phased cubic spinel structure has formed after annealing of the mechanical alloyed samples at 950 degrees C, and also in solid state routed samples. The single phase has not formed for the samples at low Co content (x = 0.1), but the single phased cubic spinel structure is stabilized for the higher value of Co content (x = 0.3, 0.5). All samples showed FM loop at room temperature. The FM parameters (magnetization, squareness, coercivity) of the mechanically alloyed samples after annealing at 950 degrees C showed higher values in comparison with as milled and solid state routed samples with similar composition. Amongst the studied samples, the composition Co0.9Fe2.1O4 (for x = 0.3) exhibited better FM properties in comparison with samples for the compositions x = 0.1 and 0.5. The present work highlighted few more unusual ferromagnetic features, e.g., different types of exchange bias effect, applied field controlled freezing of the ferromagnetic domains, tailoring of the Verwey transition of Fe3O4 in the presence of AFM Co3O4, and field driven de-pinning of the domain wall motion at lower temperature that can be manipulated for developing next generation advanced magnetic ferrites.

• 出版日期2013-11-25