Hydrogenation of allyl alcohols catalyzed by aqueous palladium and platinum nanoparticles

作者:Di Pietrantonio Krystel; Coccia Francesca; Tonucci Lucia; d' Alessandro Nicola; Bressan Mario
来源:RSC Advances, 2015, 5(84): 68493-68499.
DOI:10.1039/c5ra13840j

摘要

A series of Pd and Pt nanoparticles (NPs) was prepared starting from the corresponding metal ions and lignosulphonates; NPs were tested as catalysts for allyl alcohols hydrogenation in water at room temperature and pressure. All NPs were active with sharp differences in conversions and selectivities: Pt NPs formed mainly saturated alcohols, whereas Pd NPS were more active, but less selective, forming, in addition to saturated alcohols, also isomeric unsaturated alcohols and aldehydes, both saturated and unsaturated.

  • 出版日期2015