Stable isotope (delta O-18, delta D, delta Cl-37) evidence for multiple fluid histories in mid-Atlantic abyssal peridotites (ODP Leg 209)

作者：Barnes Jaime D^*; Paulick Holger; Sharp Zachary D; Bach Wolfgang; Beaudoin Georges

来源：Lithos, 2009, 110(1-4): 83-94.

DOI：10.1016/j.lithos.2008.12.004

• Serpentinization
• Stable isotopes
• Chlorine
• IODP
• Leg 209

Serpentinized abyssal peridotites sampled by the Ocean Drilling Program Leg 209 along the mid-Atlantic Ridge near the 15 degrees 20'N Fracture Zone have been analyzed for oxygen, hydrogen, and chlorine isotope compositions in order to determine isotopic behavior under a wide range of serpentinization conditions and place constraints on fluid history. Oxygen and hydrogen thermometry suggests peak serpentinization temperatures of 300-500 degrees C. Serpentine separates have low delta D values possibly due to a magmatic fluid component or low-temperature exchange during seafloor weathering.
Chlorine geochemistry focused on three holes: 1274A and 1272A (serpentinized peridotites) and 1268A (serpentinite locally altered to talc). Concentrations of both, water-soluble chloride (WSC) and structurally bound chloride (SBC) are significantly lower at Hole 1268A compared to Holes 1274A and 1272A. The delta Cl-37 values for WSC and SBC of serpentinites in Holes 1274A and 1272A are slightly positive (avg. WSC = 0.20 parts per thousand, n=22 and avg. SBC=0.35 parts per thousand, n=22), representing typical seawater-hydration conditions commonly determined for abyssal peridotite. The SBC of serpentinites from Hole 1268A are also positive (avg. 0.63 parts per thousand); whereas, the SBC in talc-dominated samples is negative (avg= -1.22 parts per thousand). The WSC of both talc- and serpentine-dominated samples are also negative (avg.=-0.15 parts per thousand).
interpret the chlorine isotope data to preserve a record of multiple fluid events. As seawater hydrated the peridotite Cl-37 was preferentially incorporated into the forming serpentine and water-soluble salts, yielding similar delta Cl-37 values on a regional scale as sampled by Holes 1268A, 1274A and 1272A. The resultant pore fluid was left depleted in Cl-37. Locally (Hole 1268A), this evolved fluid was remobilized possibly due to the initiation of hydrothermal circulation in response to emplacement of a mafic magma body. The low delta Cl-37 pore fluids attained elevated SiO2 and sulfur concentrations due to interaction with the gabbroic intrusion and, when ascending through the surrounding serpentinite, caused formation of isotopically negative talc. This secondary fluid also flushed the preserved serpentinite of its previously formed salts, resulting in negative delta Cl-37(WSC) values. The delta Cl-37(SBC) values of the serpentinite samples remained unmodified by reaction with the secondary fluid.

• 出版日期2009-6