A [HN(BH=NH)(2)](2-) Dianion, Isoelectronic with a beta-Diketiminate

作者：Less Robert J^*; Hanf Schirin; Garcia Rodriguez Rani; Bond Andrew D; Wright Dominic S

来源：Organometallics, 2018, 37(5): 628-631.

DOI：10.1021/acs.organomet.7b00436

The 1:2 reaction of the Al(III) beta-diketiminate dihydride [{DMPnacnac}AlH2] (DMPnacnac = HC{C(Me)-N(2,6-Me-2-C6H3)}(2)) (1) with ammonia-borane (NH3BH3) gives the new complex [{DMPnacnac]Al{NHBH)(2)NH}] (3), whose [HN(BHNH)(2)](2-) dianion is isoelectronic with beta-diketiminate anions.

• 出版日期2018-3-12