Facile preparation and performance of hierarchical self-assembly MnCo2O4 nanoflakes as anode active material for lithium ion batteries

作者：Zhang, Youwei; Wang, Xianyou^*; Zhao, Qinglan; Fu, Yanqing; Wang, Hao; Shu, Hongbo

来源：Electrochimica Acta, 2015, 180: 866-872.

DOI：10.1016/j.electacta.2015.09.037

• Hierarchical self-assembly structure
• Binary metal oxides
• Nanoflake
• Lithium ion battery
• Anode active material

Hierarchical self-assembly MnCo2O4 nanoflakes with size of about 4 mu m as anode active material for Li-ion batteries (LIBs) have been prepared by a facile method. The structure and physicochemical properties of the as-prepared self-assembly MnCo2O4 nanoflakes are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption-desorption isotherm, cyclic voltammogram (CV) and galvanostatic discharge-charge tests. The results show that the as-prepared self-assembly MnCo2O4 nanoflakes display a novel multi-lamellar macrostructure with a large number of well-distributed pores. The specific surface area of the as-prepared MnCo2O4 is about 49.44 m(2) g(-1) and the average pore size is about 2.34 nm. In addition, due to the hierarchical self-assembly structure, the MnCo2O4 nanoflakes exhibit an enhanced lithium storage capacity and excellent cycling stability (925 mAh g(-1) at a current density of 100 mA g(-1) after 50 cycles). More importantly, it can render the reversible capacity of 719 mAh g(-1) after 50 cycles, even at a high current density of 400 mA g(-1), indicating its potential for high power LIB applications.

• 出版日期2015-10-20
• 单位湘潭大学