科研之友
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摘要
Transformation of the diatomics Hamiltonian operator from the laboratory- to body-fixed frame has been performed in great mathematical details by two methods: the method in which the transformation is performed directly using the chain rule of differentiation and the method in which the generalized form of multidimensional Laplacian operator is used as the starting point. To investigate the influence of the electronic spins on the motion of the molecule, the electronic spin variables are defined in the two frames and included in the transformations.
- 出版日期2015-4-15
