Mechanism of Ag-n nanocluster photoproduction from silver oxide films

作者:Peyser LA; Lee TH; Dickson RM*
来源:Journal of Physical Chemistry B, 2002, 106(32): 7725-7728.
DOI:10.1021/jp026111x

摘要

Thin AgO films are readily photoactivated at room temperature to produce dynamic, multicolored fluorescent Ag-n nanoclusters. Writing efficiencies were separately examined as functions of excitation wavelength, intensity, and environmental interactions. The effects of external conditions on written nanocluster fluorescence are interpreted in terms of a mechanistic understanding of fluorescent Ag-n nanocluster creation and subsequent spectral dynamics, illustrating the equilibrium between nanocluster creation and destruction.

  • 出版日期2002-8-15