A novel cationic heteropolyoxovanadium(IV) cluster functionalized with organic ligands: synthesis and characterization of the fully reduced species [(MnV6O6)-V-II-O-IV{(OCH2CH2)(2)N(CH2CH2OH)}(6)]Cl-2

作者：Khan MI^*; Tabussum S; Doedens RJ

来源：Chemical Communications, 2003, (4): 532-533.

DOI：10.1039/b211195k

The solvothermal reaction of (HOCH2CH2)(3)N with [(n-C4H9)(4)N](3)[H3V10O28] and MnCl2.4H(2)O in CH3CN and CH3OH yields a novel cationic heteropolyoxovanadium(iv) cluster, [(MnV6O6)-V-II-O-IV{(OCH2CH2)(2)N(CH2CH2OH)}(6)](2+), containing a fully reduced new cyclic (MnV6N6O18} core with the Anderson structure.

• 出版日期2003