Nickel(II) thiosemicarbazone complex catalyzed Mizoroki-Heck reaction

作者：Suganthy Pandimuni Kalpaga; Prabhu Rupesh Narayana; Sridevi Venugopal Shamugham^*

来源：Tetrahedron Letters, 2013, 54(42): 5695-5698.

DOI：10.1016/j.tetlet.2013.08.018

• Thiosemicarbazone ligand
• Nickel(II) complex
• Crystal structure
• Mizoroki-Heck reaction

Convenient synthesis of a new square planar nickel(II) naphthaldehyde thiosemicarbazone complex has been described. The composition of the complex has been established by elemental analysis, spectral methods, and single crystal X-ray crystallography. The new complex acts as an active homogeneous catalyst for the Mizoroki-Heck reaction of electron deficient (activating) and electron rich (deactivating) aryl bromides with various olefins under optimized conditions.

• 出版日期2013-10-16