A Ni-P@NiCo LDH core-shell nanorod-decorated nickel foam with enhanced areal specific capacitance for high-performance supercapacitors

作者：Xing, Jiale; Du, Jing; Zhang, Xuan; Shao, Yubo; Zhang, Ting; Xu, Cailing^*

来源：Dalton Transactions, 2017, 46(30): 10064-10072.

DOI：10.1039/c7dt01910f

• DOUBLE HYDROXIDE NANOSHEETS
• LAYERED DOUBLE HYDROXIDES
• CORE/SHELL NANOWIRE ARRAYS
• BINDER-FREE ELECTRODE
• HYDROGEN EVOLUTION
• ASYMMETRIC SUPERCAPACITOR
• CARBON CLOTH
• EFFICIENT
• PHOSPHIDE
• ELECTROCATALYST

Recently, transition metal-based nanomaterials have played a key role in the applications of supercapacitors. In this study, nickel phosphide (Ni-P) was simply combined with NiCo LDH via facile phosphorization of Ni foam and subsequent electrodeposition to form core-shell nanorod arrays on the Ni foam; the Ni-P@ NiCo LDH was then directly used for a pseudocapacitive electrode. Owing to the splendid synergistic effect between Ni-P and NiCo LDH nanosheets as well as the hierarchical structure of 1D nanorods, 2D nanosheets, and 3D Ni foam, the hybrid electrode exhibited significantly enhanced electrochemical performances. The Ni-P@ NiCo LDH electrode showed a high specific capacitance of 12.9 F cm(-2) at 5 mA cm(-2) (3470.5 F g(-1) at a current density of 1.3 A g(-1)) that remained as high as 6.4 F cm-2 at a high current density of 100 mA cm(-2) (1700 F g(-1) at 27 A g(-1)) and excellent cycling stability (96% capacity retention after 10 000 cycles at 40 mA cm(-2)). Furthermore, the asymmetric supercapacitors (ASCs) were assembled using Ni-P@ NiCo LDH as a positive electrode and activated carbon (AC) as a negative electrode. The obtained ASCs delivered remarkable energy density and power density as well as good cycling performance. The enhanced electrochemical activities open a new avenue for the development of supercapacitors.

• 出版日期2017-8-14
• 单位兰州大学