A Cu Nanoparticle Embedded in Electrospundoped Carbon Nanofibers as Efficient Catalysts for Ullmann O-Arylation of Aryl Halides with Various Phenols

作者：Zhang, Chenglin; Li, Chunping^*; Bai, Jie; Li, Hengyu

来源：Catalysis Letters, 2015, 145(9): 1764-1770.

DOI：10.1007/s10562-015-1566-8

• Electrospinning
• Carbon nanofibers
• Preparation
• Ullmann O-arylation

Carbon nanofibers supported copper nanoparticles (CuNPs/CNFs) catalyst was synthesized by electrospinning in the high-pressure hydrogenation method, and the high-temperature calcination. The catalyst was characterized by scanning electron microscope, transmission electron microscope, energy dispersive spectrometer, and X-ray photoelectron spectroscopy. The CuNPs/CNFs catalyst was used for Ullmann-type couplings under ligand-free conditions, and the results showed that the CuNPs/CNFs catalyst had a good catalytic activity for Ullmann O-arylation of aryl halides with various phenols.
The schematic illustration: Preparation process of CuNPs/CNFs catalyst.
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• 出版日期2015-9
• 单位内蒙古工业大学