A Structural Electrical Conductivity Model for Oxide Melts

作者：Thibodeau Eric; Jung In Ho^*

来源：Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 2016, 47(1): 355-383.

DOI：10.1007/s11663-015-0458-z

A structural electrical conductivity model for oxide melts was developed based on the Nernst-Einstein relationship of ionic conductivity. In the description of ionic conductivity, the effective diffusivities of cations in oxide slags were described as a function of the polymerization of the melt. The polymerization of oxide melts was calculated from the Modified Quasichemical Model, taking into account the short-range ordering in slags. The parameters of this conductivity model were fixed to reproduce the electrical conductivity data in unary and binary melts, and the model can well predict the conductivity data in ternary and higher order system without any additional model parameters. The model is successfully applied to the CaO-MgO-MnO-PbO-Al2O3-SiO2 system.

• 出版日期2016-2
• 单位McGill