A 2-fold interpenetrated framework based on tetranuclear heterometallic cluster: Synthesis, structure and magnetic properties

作者：Liu Guang Xiang^*; Xu Heng; Ren Xiao Ming

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2008, 634(5): 927-930.

DOI：10.1002/zaac.200700537

• carboxylate ligand
• heterometallic complex
• alpha-Po
• magnetic property

A 2-fold parallel interpenetrated polymer, ZnCo(OH)(pheno)(p-BDC)(1.5)center dot H2O (1) (pheno = phenanthrene-9, 10-dione; p-BDC = 1,4-benzenedicarboxylate) has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, ICP and single crystal X-ray diffraction. Complex I crystallizes in the orthorhombic space group Pbca and affords a three-dimensional (3D) six-connected alpha-Po network. The magnetic behavior for 1 was studied in the temperature range of 1.8-300 K.

• 出版日期2008
• 单位安庆师范大学