An Efficient Approach to the Synthesis of Novel Pyrene-Fused Azaacenes

作者：Feng Xing; Iwanaga Fumitaka; Hu Jian Yong^*; Tomiyasu Hirotsugu; Nakano Masahiro; Redshaw Carl; Elsegood Mark R J; Yamato Takehiko

来源：Organic Letters, 2013, 15(14): 3594-3597.

DOI：10.1021/ol401438a

An efficient synthetic approach for functionalization of both the active sites (1,3-) and the K-region (4,5,9,10-) of pyrene was accomplished by bromination and oxidation with considerable yield. These novel pyrene-fused azaacenes were thoroughly investigated by X-ray diffraction studies, electrochemistry, and DFT calculations.

• 出版日期2013-7-19